Search results for "statistical [methods]"

showing 10 items of 1664 documents

Cavity-induced bifurcation in classical rate theory

2022

We show how coupling an ensemble of bistable systems to a common cavity field affects the collective stochastic behavior of this ensemble. In particular, the cavity provides an effective interaction between the systems, and parametrically modifies the transition rates between the metastable states. We predict that the cavity induces a collective phase transition at a critical temperature which depends linearly on the number of systems. It shows up as a spontaneous symmetry breaking where the stationary states of the bistable system bifurcate. We observe that the transition rates slow down independently of the phase transition, but the rate modification vanishes for alternating signs of the …

Chemical Physics (physics.chem-ph)Quantum PhysicsStatistical Mechanics (cond-mat.stat-mech)Physics - Chemical PhysicsFOS: Physical sciencesPhysics::OpticsQuantum Physics (quant-ph)Condensed Matter - Statistical Mechanics
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Recent achievements in ab initio modelling of liquid water

2013

The application of newly developed first-principle modeling techniques to liquid water deepens our understanding of the microscopic origins of its unusual macroscopic properties and behaviour. Here, we review two novel ab initio computational methods: second-generation Car-Parrinello molecular dynamics and decomposition analysis based on absolutely localized molecular orbitals. We show that these two methods in combination not only enable ab initio molecular dynamics simulations on previously inaccessible time and length scales, but also provide unprecedented insights into the nature of hydrogen bonding between water molecules. We discuss recent applications of these methods to water cluste…

Chemical Physics (physics.chem-ph)Statistical Mechanics (cond-mat.stat-mech)Biological Physics (physics.bio-ph)Physics - Chemical PhysicsSoft Condensed Matter (cond-mat.soft)FOS: Physical sciencesPhysics - Biological PhysicsComputational Physics (physics.comp-ph)Condensed Matter - Soft Condensed MatterPhysics - Computational PhysicsCondensed Matter - Statistical Mechanics
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Levy flights in confining environments: Random paths and their statistics

2013

We analyze a specific class of random systems that are driven by a symmetric L\'{e}vy stable noise. In view of the L\'{e}vy noise sensitivity to the confining "potential landscape" where jumps take place (in other words, to environmental inhomogeneities), the pertinent random motion asymptotically sets down at the Boltzmann-type equilibrium, represented by a probability density function (pdf) $\rho_*(x) \sim \exp [-\Phi (x)]$. Since there is no Langevin representation of the dynamics in question, our main goal here is to establish the appropriate path-wise description of the underlying jump-type process and next infer the $\rho (x,t)$ dynamics directly from the random paths statistics. A pr…

Chemical Physics (physics.chem-ph)Statistics and ProbabilityPhysicsStatistical Mechanics (cond-mat.stat-mech)LogarithmFOS: Physical sciencesProbability density functionContext (language use)Mathematical Physics (math-ph)Function (mathematics)Condensed Matter PhysicsStability (probability)Lévy flightPhysics - Chemical PhysicsPhysics - Data Analysis Statistics and ProbabilityStatisticsMaster equationInvariant (mathematics)Data Analysis Statistics and Probability (physics.data-an)Condensed Matter - Statistical MechanicsMathematical Physics
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Modeling of biomolecular machines in non-equilibrium steady states

2021

Numerical computations have become a pillar of all modern quantitative sciences. Any computation involves modeling--even if often this step is not made explicit--and any model has to neglect details while still being physically accurate. Equilibrium statistical mechanics guides both the development of models and numerical methods for dynamics obeying detailed balance. For systems driven away from thermal equilibrium such a universal theoretical framework is missing. For a restricted class of driven systems governed by Markov dynamics and local detailed balance, stochastic thermodynamics has evolved to fill this gap and to provide fundamental constraints and guiding principles. The next step…

Chemical Physics (physics.chem-ph)Thermal equilibriumStatistical Mechanics (cond-mat.stat-mech)Markov chainComputer scienceComputationComplex systemDegrees of freedom (physics and chemistry)FOS: Physical sciencesGeneral Physics and AstronomyDetailed balanceStatistical mechanicsCondensed Matter - Soft Condensed MatterModels BiologicalMultiscale modelingPhysics - Chemical PhysicsThermodynamicsSoft Condensed Matter (cond-mat.soft)Statistical physicsPhysical and Theoretical ChemistryCondensed Matter - Statistical MechanicsThe Journal of Chemical Physics
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Dynamics of Two Picophytoplankton Groups in Mediterranean Sea: Analysis of the Deep Chlorophyll Maximum by a Stochastic Advection-Reaction-Diffusion …

2013

A stochastic advection-reaction-diffusion model with terms of multiplicative white Gaussian noise, valid for weakly mixed waters, is studied to obtain the vertical stationary spatial distributions of two groups of picophytoplankton, i.e., picoeukaryotes and Prochlorococcus, which account about for 60% of total chlorophyll on average in Mediterranean Sea. By numerically solving the equations of the model, we analyze the one-dimensional spatio-temporal dynamics of the total picophytoplankton biomass and nutrient concentration along the water column at different depths. In particular, we integrate the equations over a time interval long enough, obtaining the steady spatial distributions for th…

ChlorophyllPopulation DynamicsPopulation ModelingRandom processeAtmospheric scienceschemistry.chemical_compoundTheoretical EcologyWater columnMediterranean seaDeep chlorophyll maximumCalculusMultidisciplinaryEcologybiologyEcologyApplied MathematicsPhysicsQStatisticsRComplex SystemsStochastic differential equationsInterdisciplinary PhysicsMedicineDeep chlorophyll maximumProchlorococcusResearch ArticleChlorophyll aScienceStatistical MechanicsDifferential EquationsPhytoplanktonMarine ecosystemMediterranean SeaSpatial ecologyStatistical MethodsPhytoplankton dynamicBiologyComputerized SimulationsStochastic ProcessesPopulation BiologyAdvectionComputational BiologyRandom VariablesModels TheoreticalSpatial ecology; Marine ecosystems; Phytoplankton dynamics; Deep chlorophyll maximum; Random processes; Stochastic differential equationsProbability Theorybiology.organism_classificationMarine EnvironmentsSettore FIS/07 - Fisica Applicata(Beni Culturali Ambientali Biol.e Medicin)Nonlinear DynamicschemistryChlorophyllComputer SciencePhytoplanktonEcosystem ModelingMathematicsEcological EnvironmentsPLoS ONE
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Adaptive trial design: a general methodology for censored time to event data.

2008

Adaptive designs allow a clinical trial design to be changed according to interim findings without inflating type I error. The Inverse Normal method can be considered as an adaptive generalization of classical group sequential designs. The use of the Inverse Normal method for censored survival data was demonstrated only for the logrank statistic. However, the logrank statistic is inefficient in the presence of nuisance covariates affecting survival. We demonstrate, how the Inverse Normal method can be applied to Cox regression analysis. The required independence between test statistics of the different stages of the trial can be obtained by two different approaches. One is using the indepen…

Clinical Trials as Topicbusiness.industryProportional hazards modelNormal DistributionRegression analysisGeneral MedicineSurvival AnalysisTimeNormal distributionResearch DesignData Interpretation StatisticalStatisticsCovariateEconometricsMedicineHumansPharmacology (medical)Computer SimulationbusinessStatisticIndependence (probability theory)Statistical hypothesis testingType I and type II errorsProportional Hazards ModelsRandomized Controlled Trials as TopicContemporary clinical trials
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V: p-Werte: Was sie besagen und was nicht …

2002

Both an extensive data description and an explicit assessment of a study result's statistical significance should be presented in the result section of a clinical trial report. Whereas the description illustrates the order and clinical relevance of the study findings, the statistical significance describes its generalizability to patients not included in the clinical trial: Despite the random recruitment of patients into a trial, the study results may fail to represent clinical reality (for example the trial might show falsely positive efficacy findings, whereas in "clinical reality" efficacy appears rather limited). A p value measures the statistical significance of a study result -- the s…

Clinical trialResearch designOphthalmologyRelative riskStatistical significanceClinical significanceGeneralizability theoryp-valuePsychologyClinical psychologyStatistical hypothesis testingKlinische Monatsblätter für Augenheilkunde
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Statistical mechanics of fullerene coalescence growth

2006

Among the different carbon allotropes fullerenes are exceptionally intriguing for their spheroidal topology out of pentagons and hexagons. However, the dominant formation mode is still ambiguous. Here, we analyze the fullerene formation process by the statistical analysis of fullerene sizes produced in a laser-induced microplasma finding that a simple two-parameter lognormal distribution describes impressively well the cluster frequencies under various conditions. Our findings clearly reveal coalescent growth following a classical collision dynamics and disagree with several earlier assumptions.

Coalescence (physics)PhysicsCollision dynamicsClassical mechanicsFullereneChemical physicsLog-normal distributionStatistical analysisStatistical mechanicsCondensed Matter PhysicsElectronic Optical and Magnetic MaterialsCoalescent theoryPhysical Review B
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Channel selection in Cognitive Radio Networks: A Switchable Bayesian Learning Automata approach

2013

We consider the problem of a user operating within a Cognitive Radio Network (CRN) which involves N channels each associated with a Primary User (PU). The problem consists of allocating a channel which, at any given time instant is not being used by a PU, to a Secondary User (SU). Within our study, we assume that a SU is allowed to perform “channel switching”, i.e., to choose an alternate channel S times (where S +1 ≤ N) if the previous choice does not lead to a channel which is vacant. The paper first presents a formal probabilistic model for the problem itself, referred to as the Formal Secondary Channel Selection (FSCS) problem, and the characteristics of the FSCS are then analyzed. Ther…

Cognitive radioTheoretical computer sciencebusiness.industryComputer scienceBayesian probabilitySampling (statistics)Statistical modelArtificial intelligenceBayesian inferencebusinessProbability vectorCommunication channelAutomaton2013 IEEE 24th Annual International Symposium on Personal, Indoor, and Mobile Radio Communications (PIMRC)
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Aggregation and sedimentation of active Brownian particles at constant affinity.

2019

We study the motility-induced phase separation of active particles driven through the interconversion of two chemical species controlled by ideal reservoirs (chemiostats). As a consequence, the propulsion speed is non-constant and depends on the actual inter-particle forces, enhancing the positive feedback between increased density and reduced motility that is responsible for the observed inhomogeneous density. For hard discs, we find that this effect is negligible and that the phase separation is controlled by the average propulsion speed. For soft particles and large propulsion speeds, however, we predict an observable impact on the collective behavior. We briefly comment on the reentrant…

Collective behaviorMaterials scienceStatistical Mechanics (cond-mat.stat-mech)010304 chemical physicsFOS: Physical sciencesGeneral Physics and AstronomyObservablePropulsionSedimentation010402 general chemistry01 natural sciences0104 chemical sciencesChemical speciesChemical physics0103 physical sciencesPhysical and Theoretical ChemistryConstant (mathematics)Condensed Matter - Statistical MechanicsBrownian motionPositive feedbackThe Journal of chemical physics
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